Scaling up experiments of honeycomb catalysts for oxidation of hydrogen and methane gases

For a large volume air cleanup system in nuclear fusion facility honeycomb type oxidizing catalyst offers more useful advantage in terms of their low pressure drop than the conventional particle packed bed. Scaling up examination of 35 times large volume Pd catalyst deposit on metal honeycomb Al–Cr-steel alloy had been performed comparing with fundamental small size honeycomb. The catalyst was heated up to over 400 °C with stepwise by combined the inner and external heaters under various flow rate of processing gas containing various concentrations of hydrogen and methane. Then oxidizing reaction rates and the catalytic activation energies were evaluated and thermal property of catalyst bed was estimated considering exothermic oxidizing reaction in the process gas. As a result it was revealed that the scaling up honeycomb catalyst bed would be practically useful for the air cleanup system.     

Performance Comparison of Circuits for Pole‐Mounted STATCOM Using SiC Devices

The recent years have seen an increasing trend in the cumulative installed capacity of distributed generators. As a result, voltage management may become difficult in existing power distribution systems in the future. A STATCOM (STAtic synchronous COMpensator) is a promising option for solving this problem because it can control reactive power rapidly and continuously. For a distribution system, STATCOM needs to be pole‐mounted to realize its low cost. However, a transformer for a STATCOM is large and heavy, and hence it is difficult to install a STATCOM on a distribution pole. We adopt a transformerless STATCOM to reduce STATCOM size and use SiC devices with low‐loss performance to obtain a more compact and efficient STATCOM. There are a large number of circuits available for a STATCOM, and there has been considerable research on performance comparisons among these circuits. However, these comparisons were drawn under different conditions, including switching frequency and level number for the circuits. In addition, these comparisons do not include the use of SiC devices. We made an equitable comparison for a 100 kVa pole‐mounted STATCOM using SiC devices. We discuss the performance and characteristics of each circuit in terms of efficiency and volume.     

Package Design of Ready-to-Drink Coffee Beverages Based on Food <Emphasis Type="Italic">Kansei</Emphasis> Model—Effects of Straw and Cognition Terms on Consumer’s Pleasantness

To design a consumer-oriented package that complements the taste and aroma of ready-to-drink chilled-cup coffee beverages by using the food kansei model, the effects of the diameter and the color of drinking straws as well as the cognition terms of coffee on consumer sensory characteristics and preferences were investigated. Variance and factor analyses of the sensory scores for chilled-cup coffee with milk and sugar using straws of different diameters, as rated by consumer panelists, extracted two perceived factors (F1, contribution ratio 36.5%, and F2, 28.6%). A two-dimensional plot of the average F1 and F2 scores of 123 panelists showed that the perceived characteristics of the same taste and aroma varied according to the straw diameter. An image investigation of different straw colors and another sensory evaluation using “black,” “brown,” and “green” straws were also performed. A principal component analysis of the image data revealed that the sensory characteristics of coffee with milk and sugar were imaged from the straw color. The second evaluation suggested that the images of straw colors affected the sensory characteristics. In addition, cluster and multiple-comparison analyses of Internet research data from consumers regarding the cognition terms for coffee exhibited three clusters representing the cognitive characteristics of terms by consumers and by developers and the differences of attractiveness degree on the cognition terms due to the consumers’ personal attributes. These studies provide useful information for the development of packages of chilled-cup coffee beverages.     

A Method for Reducing the Dead‐Time Voltage and Impedance Voltage in a Series Voltage Compensator

Many research groups are developing series voltage compensators. In a series converter, since a transformer is used in series in the power system, the power system current flows into the voltage source inverter through the transformer. The inverter current, which is determined by the transformation ratio, gives rise to an error voltage that consists of a dead‐time voltage and an impedance voltage. The error voltage is generated even when the reference voltage is zero. This paper describes the mechanism by which the error voltage occurs and proposes a method for reducing the error voltage. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 186(3): 85–93, 2014; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.22333     

Impact of Dynamic Interlayer Interactions on Thermal Conductivity of Ca3Co4O9

The phonon thermal conductivity of misfit-layered Ca₃Co₄O₉ has been calculated by perturbed molecular dynamics using a classical force field. Detailed numerical analyses reveal that, in spite of its smaller cross-sectional area, the CoO₂ layer transports more heat than the thicker rock salt (RS) layer, although its local thermal conduction is more suppressed than in another layered cobaltite, Na _x CoO₂. The origins of these differences have been elucidated through careful examination of the atomic arrangements in each layer. Since thermal conduction in the RS layer can be reduced without deteriorating electronic properties for which the CoO₂ layer is responsible, it is suggested that the RS layer should be modified to further suppress the overall in-plane thermal conductivity. Computational experiments with increasing number of Ca–O planes in the RS layer showed the opposite trend to what can be predicted based on the misfit between two dissimilar layers. Further analyses to reveal the origin of these unexpected results provide yet another strategy to further decrease the thermal conductivity, namely to control the dynamic interference between atoms across the interface between two layers.     

Effect of Vacuum Heat Treatment on Electron-Beam-Irradiation-Cured Polycarbosilane Fibers

Electron-beam-cured polycarbosilane fibers were heat-treated at 673–1773 K in a tube evacuated to 1.3 × 10⁻¹ Pa and then exposed at 1873 K in argon. The effect of vacuum heat treatment on improving the high-temperature stability of low-oxygen SiC fibers was investigated by examining gas evolution, grain growth, surface composition, tensile strength, and morphology. The fibers heat-treated at <1173 K lost strength, because of the vigorous generation of residual hydrogen. A minute amount of oxygen in the atmosphere caused the active oxidation of SiC during heat treatment at >1673 K, resulting in severe strength degradation for the as-heat-treated fibers. Vacuum heat treatment at 1573 K provided the best characteristics in low-oxygen SiC fibers.     

Challenges Upon Reactive Plasma Spray Nitriding: Al Powders and Fabrication of AlN Coatings as a Case Study

Reactive plasma spraying (RPS) is a promising technology for the in situ formation of several ceramic coatings. The focus of this paper is to summarize the state of our current knowledge about the RPS process and using the nitriding of Al particles and the fabrication of aluminum nitride coatings, as a case study. The aspects and challenges in this process such as the influence of the plasma power, in-flight time, particle size, nitriding mechanism, splat morphology, in-flight particle diagnostics, N₂ plasma gas, and the feeding rate on the RPS process are analyzed and discussed.     

Advantage of Sodium Polyoxyethylene Lauryl Ether Carboxylate as a Mild Cleansing Agent

Five anionic surfactants widely used in commercial skin cleansers were studied: sodium polyoxyethylene lauryl ether carboxylate (EC), sodium polyoxyethylene alkyl ether sulfate (ES), sodium dodecyl sulfate, potassium laurate, and N-cocoyl-l-glutamic acid monosodium salt. The amount of surfactant from aqueous solution adsorbed into the stratum corneum (SC), the degree of SC swelling, the change of the secondary structure of SC proteins (denaturation). The surface tension of surfactant–zein mixed solutions, and the solubilization behavior of zein were measured. Results showed that EC had the lowest adsorption into SC, the lowest SC swelling, and lowest denaturation of SC proteins. Low interactions between surfactants and SC proteins were also observed for EC/ES mixture solutions as well as. Mixing EC with ES good foaming performance. The EC/ES mixture, at about 1:1 ratio, is an excellent surfactant system for skin cleanser applications having cleansing characteristics and mildness to the skin.